Asymmetry effect of novel per(fluoroalkylsulfonyl)imide anions in pyrrolidinium ionic liquids
2013; Royal Society of Chemistry; Volume: 3; Issue: 39 Linguagem: Inglês
10.1039/c3ra42980f
ISSN2046-2069
AutoresSebastian Jeremias, Maria Carewska, L. Conte, Stefano Passerini, Giovanni Battista Appetecchi,
Tópico(s)Organic and Molecular Conductors Research
ResumoIonic liquids based on the N-butyl-N-methylpyrrolidinium, (PYR14)+, cation and different per(fluoroalkylsulfonyl)imide anions, having symmetric, (IM11)−, moderately asymmetric, (IM24)−, highly asymmetric, (IM14)− and (IMT4)−, and cyclic, (IM3)− structures, were properly synthesized. A few of the presented per(fluoroalkylsulfonyl)imide ions have never been reported in the literature as ionic liquid anions. The thermal and transport properties of the ionic liquid materials, having a common cation, were investigated and correlated with the structure of the per(fluoroalkylsulfonyl)imide anion. The results have indicated that the symmetry as well as the steric hindrance of the anion affect the melting point and the crystallization kinetics as well as the ion conduction and the self-diffusion coefficient of the ionic liquids. The conductivity data are in good agreement with the thermal measurements.
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