On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes
2010; Royal Society of Chemistry; Volume: 39; Issue: 44 Linguagem: Inglês
10.1039/c0dt01071e
ISSN1477-9234
AutoresClara J. Durango-García, J. Óscar C. Jiménez‐Halla, Marcela López‐Cardoso, Virginia Montiel‐Palma, Miguel‐Ángel Muñoz‐Hernández, Gabriel Merino,
Tópico(s)N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
ResumoThe iridum-gallyl complex MeIr(PCy(3))(2)(GaMe(2))(Cl*GaMe(3)) exhibits a short Ir-Ga bond length of 2.381(1)-2.389(2) Å. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir-Ga single bond but highlight a π orbital contribution.
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