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Ammonia Coordination Introducing a Magnetic Moment in an On‐Surface Low‐Spin Porphyrin

2013; Wiley; Volume: 52; Issue: 17 Linguagem: Inglês

10.1002/anie.201208028

ISSN

1521-3773

Autores

Christian Wäckerlin, Kartick Tarafder, Ján Girovský, Jan Nowakowski, Tatjana Hählen, Aneliia Shchyrba, Dorota Siewert, Armin Kleibert, F. Nolting, Peter M. Oppeneer, Thomas A. Jung, Nirmalya Ballav,

Tópico(s)

Surface Chemistry and Catalysis

Resumo

Angewandte Chemie International EditionVolume 52, Issue 17 p. 4568-4571 Communication Ammonia Coordination Introducing a Magnetic Moment in an On-Surface Low-Spin Porphyrin† Christian Wäckerlin, Christian Wäckerlin Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorDr. Kartick Tarafder, Dr. Kartick Tarafder Department of Physics and Astronomy, University of Uppsala, Box 516, 75120 Uppsala (Sweden) Current address: Materials Science Division, Lawrence, Berkeley National Laboratory, Berkeley, CA 94720 (USA)Search for more papers by this authorJan Girovsky, Jan Girovsky Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorJan Nowakowski, Jan Nowakowski Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorTatjana Hählen, Tatjana Hählen Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorAneliia Shchyrba, Aneliia Shchyrba Department of Physics, University of Basel, 4056 Basel (Switzerland)Search for more papers by this authorDr. Dorota Siewert, Dr. Dorota Siewert Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorDr. Armin Kleibert, Dr. Armin Kleibert Swiss Light Source, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorProf. Frithjof Nolting, Prof. Frithjof Nolting Swiss Light Source, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorProf. Peter M. Oppeneer, Prof. Peter M. Oppeneer Department of Physics and Astronomy, University of Uppsala, Box 516, 75120 Uppsala (Sweden)Search for more papers by this authorProf. Thomas A. Jung, Corresponding Author Prof. Thomas A. Jung [email protected] Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland) Thomas A. Jung, Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland) Nirmalya Ballav, Department of Chemistry, Indian Institute of Science Education and Research, Pune 411008 (India)Search for more papers by this authorProf. Nirmalya Ballav, Corresponding Author Prof. Nirmalya Ballav [email protected] Department of Chemistry, Indian Institute of Science Education and Research, Pune 411008 (India) Thomas A. Jung, Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland) Nirmalya Ballav, Department of Chemistry, Indian Institute of Science Education and Research, Pune 411008 (India)Search for more papers by this author Christian Wäckerlin, Christian Wäckerlin Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorDr. Kartick Tarafder, Dr. Kartick Tarafder Department of Physics and Astronomy, University of Uppsala, Box 516, 75120 Uppsala (Sweden) Current address: Materials Science Division, Lawrence, Berkeley National Laboratory, Berkeley, CA 94720 (USA)Search for more papers by this authorJan Girovsky, Jan Girovsky Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorJan Nowakowski, Jan Nowakowski Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorTatjana Hählen, Tatjana Hählen Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorAneliia Shchyrba, Aneliia Shchyrba Department of Physics, University of Basel, 4056 Basel (Switzerland)Search for more papers by this authorDr. Dorota Siewert, Dr. Dorota Siewert Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorDr. Armin Kleibert, Dr. Armin Kleibert Swiss Light Source, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorProf. Frithjof Nolting, Prof. Frithjof Nolting Swiss Light Source, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland)Search for more papers by this authorProf. Peter M. Oppeneer, Prof. Peter M. Oppeneer Department of Physics and Astronomy, University of Uppsala, Box 516, 75120 Uppsala (Sweden)Search for more papers by this authorProf. Thomas A. Jung, Corresponding Author Prof. Thomas A. Jung [email protected] Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland) Thomas A. Jung, Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland) Nirmalya Ballav, Department of Chemistry, Indian Institute of Science Education and Research, Pune 411008 (India)Search for more papers by this authorProf. Nirmalya Ballav, Corresponding Author Prof. Nirmalya Ballav [email protected] Department of Chemistry, Indian Institute of Science Education and Research, Pune 411008 (India) Thomas A. Jung, Laboratory for Micro and Nanotechnology, Paul Scherrer Institute, 5232 Villigen-PSI (Switzerland) Nirmalya Ballav, Department of Chemistry, Indian Institute of Science Education and Research, Pune 411008 (India)Search for more papers by this author First published: 19 March 2013 https://doi.org/10.1002/anie.201208028Citations: 69 † We gratefully acknowledge financial supports from the National Centre of Competence in Research Nanosciences (NCCR-Nano), Swiss Nanoscience Institute (SNI), Swiss National Science Foundation, Holcim Foundation for the Advancement of Scientific Research, Switzerland; and from the Swedish-Indian Research Links Programme and Swedish National Infrastructure for Computing (SNIC), Sweden. Part of this work was performed at the SIM beamline of the Swiss Light Source, Paul Scherrer Institut, Villigen, Switzerland. The authors sincerely thank Rolf Schelldorfer for technical support all throughout. N.B. thanks K. N. Ganesh (IISER Pune) for the support during beamtimes at SLS. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Amazing ammonia: The molecular spin state of NiII porphyrin, supported on a ferromagnetic Co surface, can be reversibly switched between spin-off (S=0) and spin-on (S=1) states upon coordination and decoordination of the gaseous ligand NH3, respectively (see picture). 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