Artigo Revisado por pares

Addition of the ortho-C–H bonds of phenol across an olefin catalysed by a chiral iridium(i) diphosphine complex

2003; Royal Society of Chemistry; Issue: 6 Linguagem: Inglês

10.1039/b211672c

ISSN

1364-548X

Autores

Romano Dorta, Antonio Togni,

Tópico(s)

Catalytic C–H Functionalization Methods

Resumo

A chiral iridium(I) diphosphine complex efficiently catalyses the unprecedented ortho-alkylation of phenol with norbornene in the absence of solvent leading to the formation of one and two C-C bonds.

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