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Raman spectra of water in the translational region

1987; Elsevier BV; Volume: 133; Issue: 5 Linguagem: Inglês

10.1016/0009-2614(87)87087-2

1873-4448

Alberto De Santis, M. Sampoli, V. Mazzacurati, Maria Antonietta Ricci,

Protein Structure and Dynamics

Light-scattering spectra of room-temperature liquid water in the region 10–400 cm−1 are presented and the isotropic component is derived. A comparison between H2O and H2S spectral shapes shows that the isotropic spectra of water arise mainly from interaction-induced mechanisms involving the first few terms of a multipolar and polarizability series expansion for the isolated molecule.