Total synthesis of bisabolane sesquiterpenoids, α-bisabol-1-one, curcumene, curcuphenol and elvirol: utility of catalytic enamine reaction in cyclohexenone synthesis
2002; Royal Society of Chemistry; Issue: 7 Linguagem: Inglês
10.1039/b200629b
ISSN1472-7781
AutoresHisahiro Hagiwara, Tomoyuki Okabe, Hiroki Ono, Vijayendra P. Kamat, Takashi Hoshi, Toshio Suzuki, Masayoshi Ando,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoTotal syntheses of α-bisabol-1-one, curcumene, curcuphenol and elvirol have been accomplished via 1,4-conjugate addition of intact aldehydes to vinyl ketones followed by an intramolecular aldol condensation.
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