Artigo Revisado por pares

Carbonyl(pyridine)iron( II ) Tetrabenzporphyrin π‐Radical Cation

1978; Wiley; Volume: 17; Issue: 12 Linguagem: Inglês

10.1002/anie.197809521

ISSN

1521-3773

Autores

Arnd Vogler, Birgit Rethwisch, Horst Kunkely, Jürgen Hüttermann,

Tópico(s)

Porphyrin Metabolism and Disorders

Resumo

“Oxidation state isomerism” exists between porphyrins which differ only in the localization of their electrons. Such a system is that of the title compound [Fe II (TBP + )(CO)(py)]⊕, in which one electron is removed from the porphyrin ring, and the corresponding (unknown) Fe III porphyrin.

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