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A Tosylimido Analogue of a Nonheme Oxoiron(IV) Complex

2006; Wiley; Volume: 45; Issue: 44 Linguagem: Inglês

10.1002/anie.200602799

1521-3773

Eric J. Klinker, Timothy A. Jackson, Michael P. Jensen, Audria Stubna, Gergely Juhász, Emile L. Bominaar, Eckard Münck, Lawrence Que,

Metal complexes synthesis and properties

High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an FeN bond (1.73 Å) that is longer than the FeO bond of its oxo analogue (1.65 Å). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z602799_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.