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Towards the Isomer‐Specific Synthesis of Higher Fullerenes and Buckybowls by the Surface‐Catalyzed Cyclodehydrogenation of Aromatic Precursors

2010; Wiley; Volume: 49; Issue: 49 Linguagem: Inglês

10.1002/anie.201005000

1521-3773

Konstantin Amsharov, Nasiba Abdurakhmanova, Sebastian Stepanow, Stephan Rauschenbach, Martin Jansen, Klaus Kern,

Carbon Nanotubes in Composites

Angewandte Chemie International EditionVolume 49, Issue 49 p. 9392-9396 Communication Towards the Isomer-Specific Synthesis of Higher Fullerenes and Buckybowls by the Surface-Catalyzed Cyclodehydrogenation of Aromatic Precursors† Dr. Konstantin Amsharov, Corresponding Author Dr. Konstantin Amsharov nasiba.a@fkf.mpg.de Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorNasiba Abdurakhmanova, Corresponding Author Nasiba Abdurakhmanova Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorDr. Sebastian Stepanow, Dr. Sebastian Stepanow Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorDr. Stephan Rauschenbach, Dr. Stephan Rauschenbach Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorProf. Martin Jansen, Prof. Martin Jansen Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorProf. Klaus Kern, Prof. Klaus Kern Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662 Institut de Physique de la Matière Condensée, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne (Switzerland)Search for more papers by this author Dr. Konstantin Amsharov, Corresponding Author Dr. Konstantin Amsharov nasiba.a@fkf.mpg.de Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorNasiba Abdurakhmanova, Corresponding Author Nasiba Abdurakhmanova Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorDr. Sebastian Stepanow, Dr. Sebastian Stepanow Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorDr. Stephan Rauschenbach, Dr. Stephan Rauschenbach Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorProf. Martin Jansen, Prof. Martin Jansen Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662Search for more papers by this authorProf. Klaus Kern, Prof. Klaus Kern Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany), Fax: (+49) 711-689-1662 Institut de Physique de la Matière Condensée, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne (Switzerland)Search for more papers by this author First published: 28 October 2010 https://doi.org/10.1002/anie.201005000Citations: 61 † We thank Zhitao Deng, Tolga Akartürk, and Ulrich Starke for their assistance with the experiments. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Fullerenes on a plate: A surface-catalyzed cyclodehydrogenation reaction enabled selective fullerene-cage formation from polycyclic organic precursors. As no CC bond rearrangement occurred during the reaction, only specifically designed precursors gave the desired fullerene (see picture). This efficient and selective condensation process opens new horizons in the directed synthesis of fullerenes and related structures. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201005000_sm_miscellaneous_information.pdf5.8 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume49, Issue49December 3, 2010Pages 9392-9396 RelatedInformation