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Synthesis of Cp*CH2PPh2 and its use as a ligand for the nickel-catalysed cross-coupling reaction of alkyl halides with aryl Grignard reagents

2006; Royal Society of Chemistry; Issue: 45 Linguagem: Inglês

10.1039/b612173j

1364-548X

Minoru Uemura, Hideki Yorimitsu, Koichiro Oshima,

Asymmetric Hydrogenation and Catalysis

A new ligand, Cp*CH2PPh2 (Cp* = 1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl), was prepared, and was used as a ligand for nickel-catalysed cross-coupling reaction of alkyl halides with aryl Grignard reagents, which nickel–phosphine complexes had never made possible.