Cathodic cleavage of heteroarylalkylsulfones : A facile route to long chain aliphatic sulfinates and relevant sulfones.
1992; Elsevier BV; Volume: 33; Issue: 16 Linguagem: Inglês
10.1016/0040-4039(92)88163-y
ISSN1873-3581
AutoresJacques Delaunay, G. Mabon, Mohamed Chaquiq El Badre, Armelle Orliac, Jacques Simonet,
Tópico(s)Organic and Inorganic Chemical Reactions
ResumoHeteroarylalkylsulfones-mainly pyridylalkylsulfones- exhibit a cathodic cleavage reaction producing alkanesulfinate anion in high yield. This reaction is tested with long chain alkyl groups and allows an easy synthesis of aliphatic sulfunic acids.
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