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A Regio-and Stereoselective Synthesis of β-Amino Alcohols

1997; Taylor & Francis; Volume: 27; Issue: 10 Linguagem: Inglês

10.1080/00397919708004077

1532-2432

Xiaolin Fu, Shi‐Hui Wu,

Carbohydrate Chemistry and Synthesis

Abstract The regio-and stereoselective ring opening of epoxide with aromatic amines catalyzed by samarium trichloride and the enantioselective ring opening of cyclohexene oxide with aniline catalyzed by lanthanide complexes were studied. Notes (a) The structure of Sphingosine is (2S,3R,4E-)-2-amino-1,3-dihydroxyl-octadeca-4-ene