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Self‐Supported and Clean One‐Step Cathodic Coupling of Activated Olefins with Benzyl Bromide Derivatives in a Micro Flow Reactor

2006; Wiley; Volume: 45; Issue: 25 Linguagem: Inglês

10.1002/anie.200600951

1521-3773

Ping He, Paul Watts, Frank Marken, Stephen J. Haswell,

Electrocatalysts for Energy Conversion

Angewandte Chemie International EditionVolume 45, Issue 25 p. 4146-4149 Communication Self-Supported and Clean One-Step Cathodic Coupling of Activated Olefins with Benzyl Bromide Derivatives in a Micro Flow Reactor† Ping He Dr., Ping He Dr. Department of Chemistry, University of Hull, Hull, HU6 7RX, UK, Fax: (+44) 148-246-6416Search for more papers by this authorPaul Watts Dr., Paul Watts Dr. Department of Chemistry, University of Hull, Hull, HU6 7RX, UK, Fax: (+44) 148-246-6416Search for more papers by this authorFrank Marken Dr., Frank Marken Dr. Department of Chemistry, University of Bath, Bath, BA2 7AY, UKSearch for more papers by this authorStephen J. Haswell Prof., Stephen J. Haswell Prof. s.j.haswell@hull.ac.uk Department of Chemistry, University of Hull, Hull, HU6 7RX, UK, Fax: (+44) 148-246-6416Search for more papers by this author Ping He Dr., Ping He Dr. Department of Chemistry, University of Hull, Hull, HU6 7RX, UK, Fax: (+44) 148-246-6416Search for more papers by this authorPaul Watts Dr., Paul Watts Dr. Department of Chemistry, University of Hull, Hull, HU6 7RX, UK, Fax: (+44) 148-246-6416Search for more papers by this authorFrank Marken Dr., Frank Marken Dr. Department of Chemistry, University of Bath, Bath, BA2 7AY, UKSearch for more papers by this authorStephen J. Haswell Prof., Stephen J. Haswell Prof. s.j.haswell@hull.ac.uk Department of Chemistry, University of Hull, Hull, HU6 7RX, UK, Fax: (+44) 148-246-6416Search for more papers by this author First published: 08 June 2006 https://doi.org/10.1002/anie.200600951Citations: 100 † We thank the EPSRC for funding. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Currently coupled: A clean microreactor-based electrosyntheses in the absence of supporting electrolyte is demonstrated and shown to feature very simple cell geometries. As exemplified for the coupling reaction of various olefins with benzyl bromides, the height of the microfluidic cell and the flow rate are crucial for the minimization of unwanted side products and optimization of yields (see picture). Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z600951_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume45, Issue25June 19, 2006Pages 4146-4149 RelatedInformation