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Heterotrimetallic Salts: Synthesis, Structures, and Superbase Reactivity of Crystalline tert ‐Butoxides [Li 4 Na 2 K 2 (O t Bu) 8 (μ‐L)] n

2008; Wiley; Volume: 47; Issue: 21 Linguagem: Inglês

10.1002/anie.200705268

1521-3773

Xuehong Wei, Qingchen Dong, Hongbo Tong, Jianbin Chao, Dian‐Sheng Liu, Michael F. Läppert,

Inorganic Chemistry and Materials

Angewandte Chemie International EditionVolume 47, Issue 21 p. 3976-3978 Communication Heterotrimetallic Salts: Synthesis, Structures, and Superbase Reactivity of Crystalline tert-Butoxides [Li4Na2K2(OtBu)8(μ-L)]n† Xuehong Wei Prof. Dr., Xuehong Wei Prof. Dr. [email protected] School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorQingchen Dong, Qingchen Dong School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorHongbo Tong, Hongbo Tong School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorJianbin Chao, Jianbin Chao School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorDiansheng Liu Prof. Dr., Diansheng Liu Prof. Dr. [email protected] School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorMichael F. Lappert Prof. Dr., Michael F. Lappert Prof. Dr. [email protected] Department of Chemistry, University of Sussex, Brighton, BN1 9QJ, UK, Fax: (+44) 1273-677196Search for more papers by this author Xuehong Wei Prof. Dr., Xuehong Wei Prof. Dr. [email protected] School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorQingchen Dong, Qingchen Dong School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorHongbo Tong, Hongbo Tong School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorJianbin Chao, Jianbin Chao School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorDiansheng Liu Prof. Dr., Diansheng Liu Prof. Dr. [email protected] School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, P. R. China, Fax: (+86) 351-7011-688Search for more papers by this authorMichael F. Lappert Prof. Dr., Michael F. Lappert Prof. Dr. [email protected] Department of Chemistry, University of Sussex, Brighton, BN1 9QJ, UK, Fax: (+44) 1273-677196Search for more papers by this author First published: 06 May 2008 https://doi.org/10.1002/anie.200705268Citations: 16 † We thank the NSFC (No. 20572065, No. 20472046) and SXNSF (20021010) for funding. L=η6:η6-C6H6 , N,N′-tmeda. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Line them up! Crystalline, polymeric arrays of heterotrimetallic (Li4Na2K2) tert-butoxides of definite composition have been obtained by mixing the individual Li, Na, and K alkoxides. In the crystal, [Li4Na2K2(μ3-OtBu)6(μ4-OtBu)2] units (see picture: Li blue, Na green, K purple, C white, O red) are joined through their terminal K ions by η6:η6-C6H6 or N,N′-tetramethylethylenediamine bridges. Citing Literature Volume47, Issue21May 13, 2008Pages 3976-3978 RelatedInformation