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Preparation, Chemical Characterization and Electronic Spectra of 6-(2-Pyridylazo)-3-Acetamidophenol and Its Metal Complexes

2000; Taylor & Francis; Volume: 33; Issue: 6 Linguagem: Inglês

10.1080/00387010009350159

1532-2289

Gehad G. Mohamed, M.A. Zayed, Nadia E. A. El‐Gamel,

Inorganic and Organometallic Chemistry

Abstract The stereochemistry of new iron (III), cobalt (II), nickel (II), copper (II), zinc (II) and cadmium (II) complexes of 6-(2-pyridylazo)-3-acetamidophenol (H2L) was studied on the basis of their analytical, spectroscopic, magnetic and conductance data. the dissociation constant of the ligand, as well as the stability constants of its metal complexes had been determined by spectrophotometric method. on the basis of infrared spectra, the coordination behaviour of the ligand to the metal ions was investigated. Magnetic susceptibility and solid reflectance spectra measurements were used to infer the structure. the isolated complexes were found to have the general formulae [M (HL). xH2O] (A).yH2O, M = Cu (II), Zn (II), Cd (II) and Fe (HI); HL = 6-(2-pyridylazo)-3-acetamido-phenol; a = acetate in the case of Cu (II) and Zn (II) or chloride in the case of Cd (II) and Fe (Ill), x = 1-3 and y=0-5. for [M (H2L).xH2O]Cl2.yH2O, M = Ni (II) and Co (II); HL = 6-(2-pyridyl-azo)-3-acetamidophenol, x=3 and y=5-6).