Single‐Step Six‐Electron Transfer in a Heptanuclear Complex: Isolation of Both Redox Forms
1995; Wiley; Volume: 33; Issue: 23-24 Linguagem: Inglês
10.1002/anie.199424601
ISSN1521-3773
AutoresJean‐Luc Fillaut, Didier Astruc, Jorge Linarès,
Tópico(s)Dendrimers and Hyperbranched Polymers
ResumoAngewandte Chemie International Edition in EnglishVolume 33, Issue 23-24 p. 2460-2462 Communication Single-Step Six-Electron Transfer in a Heptanuclear Complex: Isolation of Both Redox Forms†‡ Dr. Jean-Luc Fillaut, Dr. Jean-Luc Fillaut Laboratoire de Chimie Organique et Organométallique Université Bordeaux I, URA CNRS N° 35 351, Cours de la Liberation, F-33405 Talence Cedex (France) Telefax: Int. code + 56846646Search for more papers by this authorProf. Didier Astruc, Corresponding Author Prof. Didier Astruc Laboratoire de Chimie Organique et Organométallique Université Bordeaux I, URA CNRS N° 35 351, Cours de la Liberation, F-33405 Talence Cedex (France) Telefax: Int. code + 56846646Laboratoire de Chimie Organique et Organométallique Université Bordeaux I, URA CNRS N° 35 351, Cours de la Liberation, F-33405 Talence Cedex (France) Telefax: Int. code + 56846646Search for more papers by this authorDr. Jorge Linares, Dr. Jorge Linares Département de Recherches Physiques Université Pierre et Marie Curie, URA CNRS N° 71 Tour 22, 4, place Jussieu, F-75252 Paris Cedex (France)Search for more papers by this author Dr. Jean-Luc Fillaut, Dr. Jean-Luc Fillaut Laboratoire de Chimie Organique et Organométallique Université Bordeaux I, URA CNRS N° 35 351, Cours de la Liberation, F-33405 Talence Cedex (France) Telefax: Int. code + 56846646Search for more papers by this authorProf. Didier Astruc, Corresponding Author Prof. Didier Astruc Laboratoire de Chimie Organique et Organométallique Université Bordeaux I, URA CNRS N° 35 351, Cours de la Liberation, F-33405 Talence Cedex (France) Telefax: Int. code + 56846646Laboratoire de Chimie Organique et Organométallique Université Bordeaux I, URA CNRS N° 35 351, Cours de la Liberation, F-33405 Talence Cedex (France) Telefax: Int. code + 56846646Search for more papers by this authorDr. Jorge Linares, Dr. Jorge Linares Département de Recherches Physiques Université Pierre et Marie Curie, URA CNRS N° 71 Tour 22, 4, place Jussieu, F-75252 Paris Cedex (France)Search for more papers by this author First published: January 3, 1995 https://doi.org/10.1002/anie.199424601Citations: 93 † This research was supported by the Centre National de la Recherche Scientifique (CNRS), the Universities Bordeaux I and Paris VI, and the Région Aquitaine. We thank Prof. F. Varret and K. Boukheddaden for help with the Mössbauer spectroscopy, S. Treavett for synthetic collaboration, and Dr. F. Moulines for discussions. ‡ Dedicated to Dr. Jacqueline Zarembovitch AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The cationic heptanuclear hexaferrocenyl compound 1 can be synthesized efficiently (as the orange-red PF6 salt) by the FeCp+-induced hexaferrocenylalkylation of the hexamethylbenzene ligand of [FeCp(C6Me6)]PF6. The 6e oxidation of 1 to the heptacation and the 1 e reduction to the neutral compound are supported by cyclic voltammetry and Mössbauer spectroscopy. Citing Literature Volume33, Issue23-24January 3, 1995Pages 2460-2462 RelatedInformation
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