Phosphorus Complexes of the First Expanded Isophlorins
2009; Wiley; Volume: 16; Issue: 1 Linguagem: Inglês
10.1002/chem.200902708
ISSN1521-3765
AutoresTakahiro Miura, Tomohiro Higashino, Shohei Saito, Atsuhiro Osuka,
Tópico(s)Porphyrin Metabolism and Disorders
ResumoBisphosphorus complexes: Phosphorus complexes of octaphyrin were prepared upon the treatment of [36]octaphyrin(1.1.1.1.1.1.1.1) with PCl3 in the presence of amine and a small amount of water (see figure). Reversible redox interconversions between 38π- and 40π-electronic states were demonstrated. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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