Diferrocenyl tosyl hydrazone with an ultrastrong NH⋯Fe hydrogen bond as double click switch
2014; Royal Society of Chemistry; Volume: 51; Issue: 8 Linguagem: Inglês
10.1039/c4cc08868a
ISSN1364-548X
AutoresChristoph Förster, Philipp Veit, Vadim Ksenofontov, Katja Heinze,
Tópico(s)N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
ResumoThe ultrastrong and short intramolecular NHFe hydrogen bond in diferrocenyl hydrazone raises the barrier for intramolecular electron transfer in its mixed-valent cation and is only disrupted by double oxidation to .
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