Artigo Acesso aberto Revisado por pares

Diferrocenyl tosyl hydrazone with an ultrastrong NH⋯Fe hydrogen bond as double click switch

2014; Royal Society of Chemistry; Volume: 51; Issue: 8 Linguagem: Inglês

10.1039/c4cc08868a

ISSN

1364-548X

Autores

Christoph Förster, Philipp Veit, Vadim Ksenofontov, Katja Heinze,

Tópico(s)

N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Resumo

The ultrastrong and short intramolecular NHFe hydrogen bond in diferrocenyl hydrazone raises the barrier for intramolecular electron transfer in its mixed-valent cation and is only disrupted by double oxidation to .

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