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Self‐Assembly of Tubular Microstructures from Mixed‐Valence Metal Complexes and Their Reversible Transformation by External Stimuli

2011; Wiley; Volume: 51; Issue: 3 Linguagem: Inglês

10.1002/anie.201105080

1521-3773

Keita Kuroiwa, Masaki Yoshida, Shigeyuki Masaoka, Kenji Kaneko, Ken Sakai, Nobuo Kimizuka,

Supramolecular Chemistry and Complexes

Mix and shake: Lipid packaged dinuclear ruthenium(II,III) complexes of class III mixed-valence state produce a reversible hypochromic effect upon external physical stimuli, such as shaking, due to the arrangement of transition dipole moments. The effect is accompanied by tubular-to-ribbon structural changes (see scheme). Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.