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An extremely mild desulfurization of thiiranes; an efficient transformation from geraniol to (+)- and (−)-linalool

1994; Elsevier BV; Volume: 35; Issue: 36 Linguagem: Inglês

10.1016/s0040-4039(00)73471-x

1873-3581

Jun’ichi Uenishi, Yuhki Kubo,

Sulfur-Based Synthesis Techniques

Thiirane was transformed to alkene very efficiently at −78°C by triethylborane initiated radical reaction with tributyltin hydride. Enantiomerically pure (+)- and (−)-linalools were derived from geraniol in four steps including the alkene formation reaction.