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Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron–Ligand Coordination Strength

2013; Wiley; Volume: 52; Issue: 27 Linguagem: Inglês

10.1002/anie.201303025

1521-3773

Juan Tian, Adina Morozan, Moulay Tahar Sougrati, Michel Lefèvre, Régis Chenitz, Jean‐Pol Dodelet, Deborah J. Jones, Frédéric Jaouen,

Metal-Organic Frameworks: Synthesis and Applications

Angewandte Chemie International EditionVolume 52, Issue 27 p. 6867-6870 Communication Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron–Ligand Coordination Strength† Dr. Juan Tian, Dr. Juan Tian Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada)Search for more papers by this authorDr. Adina Morozan, Dr. Adina Morozan Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Moulay Tahar Sougrati, Dr. Moulay Tahar Sougrati Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Michel Lefèvre, Dr. Michel Lefèvre Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada)Search for more papers by this authorDr. Régis Chenitz, Dr. Régis Chenitz Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada)Search for more papers by this authorProf. Jean-Pol Dodelet, Corresponding Author Prof. Jean-Pol Dodelet dodelet@emt.inrs.ca Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada) Jean-Pol Dodelet, Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada) Frédéric Jaouen, Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Deborah Jones, Dr. Deborah Jones Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Frédéric Jaouen, Corresponding Author Dr. Frédéric Jaouen frederic.jaouen@univ-montp2.fr Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France) Jean-Pol Dodelet, Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada) Frédéric Jaouen, Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this author Dr. Juan Tian, Dr. Juan Tian Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada)Search for more papers by this authorDr. Adina Morozan, Dr. Adina Morozan Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Moulay Tahar Sougrati, Dr. Moulay Tahar Sougrati Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Michel Lefèvre, Dr. Michel Lefèvre Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada)Search for more papers by this authorDr. Régis Chenitz, Dr. Régis Chenitz Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada)Search for more papers by this authorProf. Jean-Pol Dodelet, Corresponding Author Prof. Jean-Pol Dodelet dodelet@emt.inrs.ca Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada) Jean-Pol Dodelet, Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada) Frédéric Jaouen, Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Deborah Jones, Dr. Deborah Jones Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this authorDr. Frédéric Jaouen, Corresponding Author Dr. Frédéric Jaouen frederic.jaouen@univ-montp2.fr Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France) Jean-Pol Dodelet, Institut National de la Recherche Scientifique Energie, Matériaux et Télécommunications, 1650 boulevard Lionel Boulet, Varennes (Qc) J3X 1S2 (Canada) Frédéric Jaouen, Université Montpellier 2, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon, 34095 Montpellier (France)Search for more papers by this author First published: 29 May 2013 https://doi.org/10.1002/anie.201303025Citations: 179 † We acknowledge funding by the NSERC, and by the ANR under contract 2011 CHEX 004 01. PEM=polymer electrolyte membrane. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract It's all in the detail: Highly active Fe/N/C catalysts for the oxygen-reduction reaction in polymer-electrolyte-membrane (PEM) fuel cells can be obtained from a precursor constructed from the zeolitic imidazolate framework ZIF-8 and an iron–ligand complex if, and only if, the displacement of ZnII ions from ZIF-8 by FeII ions is restricted (see picture; TPTZ=2,4,6-tris(2-pyridyl)-s-triazine). Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201303025_sm_miscellaneous_information.pdf239.1 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue27July 1, 2013Pages 6867-6870 RelatedInformation