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Perfluoroalkyl‐Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide

1997; Wiley; Volume: 36; Issue: 15 Linguagem: Inglês

10.1002/anie.199716281

1521-3773

Sabine Kainz, Daniel Koch, Walter Leitner, Wolfgang Baumann,

Organometallic Complex Synthesis and Catalysis

Angewandte Chemie International Edition in EnglishVolume 36, Issue 15 p. 1628-1630 Communication Perfluoroalkyl-Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide†‡ Sabine Kainz, Sabine Kainz Max-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deSearch for more papers by this authorDaniel Koch, Daniel Koch Max-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deSearch for more papers by this authorPriv.-Doz. Dr. Walter Leitner, Corresponding Author Priv.-Doz. Dr. Walter Leitner Max-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deMax-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deSearch for more papers by this authorDr. Wolfgang Baumann, Dr. Wolfgang Baumann Research group "Komplexkatalyse" of the Max-Planck-Gesellschaft at the Universität Rostock (Germany)Search for more papers by this author Sabine Kainz, Sabine Kainz Max-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deSearch for more papers by this authorDaniel Koch, Daniel Koch Max-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deSearch for more papers by this authorPriv.-Doz. Dr. Walter Leitner, Corresponding Author Priv.-Doz. Dr. Walter Leitner Max-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deMax-Planck-Institut für Kohlenforchung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr (Germany) Fax: Int Code +(208)306-2908 e-mail: leitner@mpi-muelheim.mpg.deSearch for more papers by this authorDr. Wolfgang Baumann, Dr. Wolfgang Baumann Research group "Komplexkatalyse" of the Max-Planck-Gesellschaft at the Universität Rostock (Germany)Search for more papers by this author First published: August 18, 1997 https://doi.org/10.1002/anie.199716281Citations: 232 † This work was supported by the Max-Planck-Gesellschaft and the Gerhard-Hess-Programm of the Deutsche Forschungsgemeinschaft. We wish to thank Dr. K. Seevogel and M. Blumenthal (Mülheim and der Ruhr) for assistance with UV/Vis measurements. We also thank Degussa AG and Hoechst AG for generous loans of chemicals. ‡ In memory of Sir Geoffrey Wilkinson AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The solubility of complexes is one decisive factor for their use as homogeneous catalysis in supercritical carbon dioxide (scCO2). Complexes with perfluoroalkyl-substituted arylphosphane ligands (shown schematically on the right), which can be prepared by a straightforward and variable synthetic methodology, exhibit high solubility in scCO2 in contrast to unsubstituted parent compounds. Citing Literature Volume36, Issue15August 18, 1997Pages 1628-1630 RelatedInformation