The O-bonded monometallic and O- and C-bonded dimetallic form of N,N-diphenylacetamide enolate with transition metals: X-ray structure of [Ph 2 N–C(CH 2 )OZr(η 5 -C 5 H 5 ) 2 (Cl)] and [Ph 2 N–C{CH 2 Cr(CO) 5 }OZr(η 5 -C 5 H 5 ) 2 (Cl)]

Artigo

The O-bonded monometallic and O- and C-bonded dimetallic form of N,N-diphenylacetamide enolate with transition metals: X-ray structure of [Ph 2 N–C(CH 2 )OZr(η 5 -C 5 H 5 ) 2 (Cl)] and [Ph 2 N–C{CH 2 Cr(CO) 5 }OZr(η 5 -C 5 H 5 ) 2 (Cl)]

1991; Royal Society of Chemistry; Issue: 17 Linguagem: Inglês

10.1039/c39910001166

ISSN

2050-5639

Autores

Patrick Veya, Carlo Floriani, Angiola Chiesi‐Villa, Carlo Guastini,

Tópico(s)

Synthetic Organic Chemistry Methods

Resumo

The N,N-diphenylacetamide enolato anion oxygen bonded to zirconium in [Ph2N–C(CH2)OZr-(η5-C5H5)2(Cl)] has been synthesised, which, when reacted with [Cr(CO)5(thf)], led to the dimetallic form of the amide enolato O-bonded to zirconium and C-bonded to chromium.

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The O-bonded monometallic and O- and C-bonded dimetallic form of N,N-diphenylacetamide enolate with transition metals: X-ray structure of [Ph 2 N–C(CH 2 )OZr(η 5 -C 5 H 5 ) 2 (Cl)] and [Ph 2 N–C{CH 2 Cr(CO) 5 }OZr(η 5 -C 5 H 5 ) 2 (Cl)]