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Enantioselective Rh-Catalyzed Arylation of N -Tosylarylimines with Arylboronic Acids

2006; American Chemical Society; Volume: 8; Issue: 12 Linguagem: Inglês

10.1021/ol060755w

1523-7060

Haifeng Duan, Yi‐Xia Jia, Lixin Wang, Qi‐Lin Zhou,

Cyclopropane Reaction Mechanisms

The asymmetric arylation of N-tosylarylimines with arylboronic acids was realized by using rhodium/(S)-ShiP as catalyst. The reaction proceeded in aqueous toluene to give diarylmethylamines in good yields with up to 96% ee. [reaction: see text]