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Selective Binding and Easy Separation of C 70 by Nanoscale Self‐Assembled Capsules

2006; Wiley; Volume: 46; Issue: 1-2 Linguagem: Inglês

10.1002/anie.200603223

1521-3773

Elisa Huerta, Gerald A. Metselaar, Alex Fragoso, Eva Santos, Carles Bó, Javier de Mendoza,

Graphene research and applications

Angewandte Chemie International EditionVolume 46, Issue 1-2 p. 202-205 Communication Selective Binding and Easy Separation of C70 by Nanoscale Self-Assembled Capsules† Elisa Huerta, Elisa Huerta Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.esSearch for more papers by this authorGerald A. Metselaar Dr., Gerald A. Metselaar Dr. Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.esSearch for more papers by this authorAlex Fragoso Dr., Alex Fragoso Dr. Department of Organic Chemistry, Universidad Autónoma de Madrid, 28049 Madrid, SpainSearch for more papers by this authorEva Santos, Eva Santos Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.esSearch for more papers by this authorCarles Bo Dr., Carles Bo Dr. Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.es Department of Inorganic and Physical Chemistry, Universitat Rovira i Virgili, 43007 Tarragona, SpainSearch for more papers by this authorJavier de Mendoza Prof., Javier de Mendoza Prof. [email protected] Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.es Department of Organic Chemistry, Universidad Autónoma de Madrid, 28049 Madrid, SpainSearch for more papers by this author Elisa Huerta, Elisa Huerta Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.esSearch for more papers by this authorGerald A. Metselaar Dr., Gerald A. Metselaar Dr. Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.esSearch for more papers by this authorAlex Fragoso Dr., Alex Fragoso Dr. Department of Organic Chemistry, Universidad Autónoma de Madrid, 28049 Madrid, SpainSearch for more papers by this authorEva Santos, Eva Santos Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.esSearch for more papers by this authorCarles Bo Dr., Carles Bo Dr. Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.es Department of Inorganic and Physical Chemistry, Universitat Rovira i Virgili, 43007 Tarragona, SpainSearch for more papers by this authorJavier de Mendoza Prof., Javier de Mendoza Prof. [email protected] Institute of Chemical Research of Catalonia (ICIQ), 43007 Tarragona, Spain, Fax: (+34) 977-920-226 http://www.iciq.es Department of Organic Chemistry, Universidad Autónoma de Madrid, 28049 Madrid, SpainSearch for more papers by this author First published: 12 December 2006 https://doi.org/10.1002/anie.200603223Citations: 121 † This work was supported by the Ministry of Science and Education of Spain (projects BQU2002-03536 and CTQ2005-06909-C02-02/BQU), the ICIQ Foundation, and Consolider Ingenio 2010 (Grant CSD2006-0003). Grants from the ICIQ Foundation (E.H., E.S., and G.A.M.) are gratefully acknowledged. We thank Prof. Pablo Ballester (ICIQ) for help and guidance in the calculation and interpretation of binding constants. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract All wrapped up: An easy, highly selective separation of C70 and the higher fullerenes has been achieved by solid–liquid extraction with a 2-ureido-4-[1H]-pyrimidinone-based scaffold which wraps around the guest as a dimeric capsule (see picture), thereby solubilizing it in THF. 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Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z603223_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume46, Issue1-2December 18, 2006Pages 202-205 ReferencesRelatedInformation