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Ionic Liquid as Reagent. A Green Procedure for the Regioselective Conversion of Epoxides to V icinal -Halohydrins Using [AcMIm]X under Catalyst- and Solvent-Free Conditions

2005; American Chemical Society; Volume: 70; Issue: 11 Linguagem: Inglês

10.1021/jo0500885

1520-6904

Brindaban C. Ranu, Subhash Banerjee,

Vanadium and Halogenation Chemistry

A variety of structurally diverse epoxides undergo facile cleavages by ionic liquid, [AcMIm]X without any catalyst and solvent to produce the corresponding vicinal halohydrins in high yields. The cleavages are considerably fast and highly regioselective.