Voltar
Artigo Acesso aberto Revisado por pares
BIBTEX RIS

Synergistic Effects Between Phosphonium‐Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives

2015; Volume: 27; Issue: 32 Linguagem: Inglês

10.1002/adma.201502037

ISSN

1521-4095

Autores

Jun Qu, William Barnhill, Huimin Luo, Harry M. Meyer, Donovan N. Leonard, Alexander K. Landauer, Bassem Kheireddin, Hong Gao, B. L. Papke, Sheng Dai,

Tópico(s)

Force Microscopy Techniques and Applications

Resumo

Unique synergistic effects between phosphonium-alkylphosphate ionic liquids (ILs) and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the remarkably 30-70× higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.

Referência(s)