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An Air‐Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

2012; Wiley; Volume: 52; Issue: 5 Linguagem: Inglês

10.1002/anie.201208432

1521-3773

Zhiqiang Weng, Weiming He, Chaohuang Chen, Richmond Lee, Davin Tan, Zhiping Lai, Dedao Kong, Yaofeng Yuan, Kuo‐Wei Huang,

Catalytic C–H Functionalization Methods

A series of copper(I) trifluoromethyl thiolate complexes have been synthesized from the reaction of CuF2 with Me3SiCF3 and S8 (see scheme; Cu red, F green, N blue, S yellow). These air-stable complexes serve as reagents for the efficient conversion of a wide range of aryl halides into the corresponding aryl trifluoromethyl thioethers in excellent yields. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.