Synthesis of new organic super acids—N-(trifluoromethylsulfonyl)imino derivatives of trifluoromethanesulfonic acid and bis(trifluoromethylsulfonyl)imide
2005; Royal Society of Chemistry; Volume: 3; Issue: 12 Linguagem: Inglês
10.1039/b503286p
ISSN1477-0539
AutoresRomute Yu. Garlyauskayte, Alexander N. Chernega, Christophe Michot, Michel Armand, Yurii L. Yagupolskii, L. M. YAGUPOL'SKII,
Tópico(s)Fluorine in Organic Chemistry
ResumoSalts of N-trifluoromethylsulfonyl derivatives of trifluoromethyl- and phenylsulfonimidoyl imides have been synthesized by two different routes. Both methods are one-pot reactions, that run in mild conditions with good yields. Two novel organic super acids: bis[N-(trifluoromethylsulfonyl)trifluoromethanesulfonimidoyl]imide and N,N'-bis(trifluoromethyl-sulfonyl)diimino trifluoromethanesulfonic acid were prepared and the structure of their potassium salts was obtained by single-crystal X-ray diffraction.
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