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Molecular Camouflage: Making Use of Protecting Groups To Control the Self‐Assembly of Inorganic Janus Particles onto Metal–Chalcogenide Nanotubes by Pearson Hardness

2011; Wiley; Volume: 50; Issue: 51 Linguagem: Inglês

10.1002/anie.201105337

1521-3773

Jugal Kishore Sahoo, Muhammad Nawaz Tahir, Faegheh Hoshyargar, B. Nakhjavan, Robert Branscheid, Ute Kolb, Wolfgang Tremel,

Advanced Photocatalysis Techniques

Hard and soft: Binding of inorganic [email protected]3O4 Janus particles to WS2 nanotubes through their Pt or Fe3O4 domains is governed by the difference in Pearson hardness: the soft Pt block has a higher sulfur affinity than the harder magnetite face; thus the binding proceeds preferentially through the Pt face. This binding preference can be reversed by masking the Pt face with an organic protecting group. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.