Bis{(2-diphenylphosphino)phenyl}mercury: a novel bidentate ligand and transfer reagent for the o-C6H4PPh2 group
1998; Royal Society of Chemistry; Issue: 21 Linguagem: Inglês
10.1039/a806494f
ISSN1364-548X
AutoresMartin A. Bennett, Marı́a Contel, David C. R. Hockless, L.L. Welling,
Tópico(s)Coordination Chemistry and Organometallics
ResumoThe compound [Hg(o-C6H4PPh2)2] behaves as a trans-spanning bidentate ditertiary phosphine in its PdCl2 complex, the two metal atoms being forced into close contact; the palladium(0) complex [Pd{(o-Ph2PC6H4)2Hg}2] undergoes reductive elimination on heating with formation of the coupled product o-Ph2PC6H4C6H4PPh2-o.
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