Turinese Stereochemistry: Eligio Perucca's Enantioselectivity and Primo Levi's Asymmetry
2009; Wiley; Volume: 48; Issue: 21 Linguagem: Inglês
10.1002/anie.200801840
ISSN1521-3773
AutoresBart Kahr, Yonghong Bing, Werner Kaminsky, Davide Viterbo,
Tópico(s)Origins and Evolution of Life
ResumoA reputation restored: Eligio Perucca (see photo) first observed the enantioselective adsorption of a racemic mixture to a chiral crystal (NaClO(3)) in Turin in 1919. However, this milestone in enantioselective chemistry and chiroptics went unnoticed. Identified previously as a coward who refused in 1941 to supervise the research of the budding stereochemist Primo Levi because of the race laws, Perucca was opposed to the fascist regime.
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