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A Single‐Molecule‐Magnetic, Cubane‐Based, Triangular Co 12 Supercluster

2007; Wiley; Volume: 46; Issue: 11 Linguagem: Romeno

10.1002/anie.200602922

ISSN

1521-3773

Autores

Ming‐Hua Zeng, Min‐Xia Yao, Hong Liang, Wei‐Xiong Zhang, Xiao‐Ming Chen,

Tópico(s)

Metal complexes synthesis and properties

Resumo

Angewandte Chemie International EditionVolume 46, Issue 11 p. 1832-1835 Communication A Single-Molecule-Magnetic, Cubane-Based, Triangular Co12 Supercluster† Ming-Hua Zeng Dr., Ming-Hua Zeng Dr. [email protected] Department of Chemistry and Chemical Engineering, GuangXi Normal University, Guilin 541004, P.R. China, Fax: (+86) 20-8411-2245Search for more papers by this authorMin-Xia Yao, Min-Xia Yao Department of Chemistry and Chemical Engineering, GuangXi Normal University, Guilin 541004, P.R. China, Fax: (+86) 20-8411-2245Search for more papers by this authorHong Liang Prof. Dr., Hong Liang Prof. Dr. Department of Chemistry and Chemical Engineering, GuangXi Normal University, Guilin 541004, P.R. China, Fax: (+86) 20-8411-2245Search for more papers by this authorWei-Xiong Zhang, Wei-Xiong Zhang MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P.R. ChinaSearch for more papers by this authorXiao-Ming Chen Prof. Dr., Xiao-Ming Chen Prof. Dr. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P.R. ChinaSearch for more papers by this author Ming-Hua Zeng Dr., Ming-Hua Zeng Dr. [email protected] Department of Chemistry and Chemical Engineering, GuangXi Normal University, Guilin 541004, P.R. China, Fax: (+86) 20-8411-2245Search for more papers by this authorMin-Xia Yao, Min-Xia Yao Department of Chemistry and Chemical Engineering, GuangXi Normal University, Guilin 541004, P.R. China, Fax: (+86) 20-8411-2245Search for more papers by this authorHong Liang Prof. Dr., Hong Liang Prof. Dr. Department of Chemistry and Chemical Engineering, GuangXi Normal University, Guilin 541004, P.R. China, Fax: (+86) 20-8411-2245Search for more papers by this authorWei-Xiong Zhang, Wei-Xiong Zhang MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P.R. ChinaSearch for more papers by this authorXiao-Ming Chen Prof. Dr., Xiao-Ming Chen Prof. Dr. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P.R. ChinaSearch for more papers by this author First published: 26 February 2007 https://doi.org/10.1002/anie.200602922Citations: 256 † Special thanks are offered to the reviewers for their helpful comments. This work was supported by NSFC (No. 30460153 & 20561001), the Scientific Foundation of GuangXi Province (No. 0447019), and the TRAPOYT of the Chinese MOE. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Extraordinary structure: An unprecedented Co12 supercluster in which three Co4O4 cubes surround a central μ6-nitrate ligand exhibits single-molecule magnet behavior. The picture shows the structure of the Co12 core and the temperature dependence of the in-phase (χ′, full symbols) and out-of-phase (χ′′, open symbols) components of the magnetic susceptibility at various ac frequencies. 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