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Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs 2 CO 3 / t -BuOH

2003; American Chemical Society; Volume: 5; Issue: 6 Linguagem: Inglês

10.1021/ol027463p

1523-7060

Jeffrey T. Bagdanoff, Evandro Maia Ferreira, Brian M. Stoltz,

Synthesis and Catalytic Reactions

The addition of Cs2CO3 and t-BuOH provides a dramatic rate acceleration in the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols while maintaining the selectivity of the process.