FeCl 2 ‐Catalyzed Selective CC Bond Formation by Oxidative Activation of a Benzylic CH Bond
2007; Wiley; Volume: 46; Issue: 34 Linguagem: Inglês
10.1002/anie.200701782
ISSN1521-3773
AutoresZhiping Li, Lin Cao, Chao‐Jun Li,
Tópico(s)Catalytic Cross-Coupling Reactions
ResumoAny old iron: Readily available and nontoxic FeCl2 effectively catalyzes CC bond formation by oxidative activation of benzylic CH bonds in the presence of tert-butyl peroxide as a stoichiometric oxidant (see scheme). The mild reaction conditions, good yields, low catalyst cost, and easy operation are the major advantages of this cross-dehydrogenation coupling reaction. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z701782_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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