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Proline-catalysed asymmetric amination of α,α-disubstituted aldehydes: synthesis of configurationally stable enantioenriched α-aminoaldehydes

2003; Royal Society of Chemistry; Issue: 19 Linguagem: Inglês

10.1039/b305465a

ISSN

1364-548X

Autores

Henning Vogt, Sylvia Vanderheiden, Stefan Bräse,

Tópico(s)

Advanced Synthetic Organic Chemistry

Resumo

Proline-catalysed amination of α,α-disubstituted racemic aldehydes with azodicarboxylates proceeds smoothly to give configurationally stable scalemic aldehydes and oxazolidinones in up to 86% ee.

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