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Hydrogen Atom Abstraction and Hydride Transfer Reactions by Iron(IV)–Oxo Porphyrins

2008; Wiley; Volume: 47; Issue: 38 Linguagem: Inglês

10.1002/anie.200802346

1521-3773

Yu Jin Jeong, Yaeun Kang, Ah‐Rim Han, Yong‐Min Lee, Hiroaki Kotani, Shunichi Fukuzumi, Wonwoo Nam,

Heme Oxygenase-1 and Carbon Monoxide

Angewandte Chemie International EditionVolume 47, Issue 38 p. 7321-7324 Communication Hydrogen Atom Abstraction and Hydride Transfer Reactions by Iron(IV)–Oxo Porphyrins† Yu Jin Jeong, Yu Jin Jeong Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441 These authors contributed equally to this work.Search for more papers by this authorYaeun Kang, Yaeun Kang Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441 These authors contributed equally to this work.Search for more papers by this authorAh-Rim Han, Ah-Rim Han Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441Search for more papers by this authorYong-Min Lee Dr., Yong-Min Lee Dr. Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441Search for more papers by this authorHiroaki Kotani Dr., Hiroaki Kotani Dr. Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST (Japan) Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7370Search for more papers by this authorShunichi Fukuzumi Prof. Dr., Shunichi Fukuzumi Prof. Dr. [email protected] Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST (Japan) Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7370Search for more papers by this authorWonwoo Nam Prof. Dr., Wonwoo Nam Prof. Dr. [email protected] Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441Search for more papers by this author Yu Jin Jeong, Yu Jin Jeong Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441 These authors contributed equally to this work.Search for more papers by this authorYaeun Kang, Yaeun Kang Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441 These authors contributed equally to this work.Search for more papers by this authorAh-Rim Han, Ah-Rim Han Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441Search for more papers by this authorYong-Min Lee Dr., Yong-Min Lee Dr. Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441Search for more papers by this authorHiroaki Kotani Dr., Hiroaki Kotani Dr. Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST (Japan) Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7370Search for more papers by this authorShunichi Fukuzumi Prof. Dr., Shunichi Fukuzumi Prof. Dr. [email protected] Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST (Japan) Science and Technology Agency (JST), Suita, Osaka 565-0871 (Japan), Fax: (+81) 6-6879-7370Search for more papers by this authorWonwoo Nam Prof. Dr., Wonwoo Nam Prof. Dr. [email protected] Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750 (Korea), Fax: (+82) 2-3277-4441Search for more papers by this author First published: 03 September 2008 https://doi.org/10.1002/anie.200802346Citations: 107 † The research at EWU was supported by KOSEF/MOST through the CRI Program, Korea, and the research at OU was supported by a Grant-in-Aid (No. 19205019) from the Ministry of Education, Culture, Sports, Science and Technology (Japan). Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract True identity revealed: The CH bond activation of alkyl aromatics by synthetic iron(IV)–oxo porphyrin species and the hydride transfer of NADH analogues to them occur through H-atom abstraction and proton-coupled electron-transfer mechanisms, respectively. Mechanistic studies revealed that iron(IV)–oxo porphyrins, not iron(IV)–oxo porphyrin π-radical cations, are the true oxidant. Citing Literature Volume47, Issue38September 8, 2008Pages 7321-7324 RelatedInformation