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Palladium-Catalyzed Synthesis of N -Vinyl Pyrroles and Indoles

2005; American Chemical Society; Volume: 70; Issue: 21 Linguagem: Inglês

10.1021/jo051450i

1520-6904

Mohammad Movassaghi, Alison E. Ondrus,

Oxidative Organic Chemistry Reactions

A stereospecific palladium-catalyzed N-vinylation of azaheterocycles with vinyl triflates is described. Cyclic and acyclic vinyl triflates along with nonnucleophilic azaheterocycles were found to be substrates for this palladium-catalyzed synthesis of N-vinyl pyrrole and indole derivatives.