Oxidant‐Free Alcohol Dehydrogenation Using a Reusable Hydrotalcite‐Supported Silver Nanoparticle Catalyst
2007; Wiley; Volume: 47; Issue: 1 Linguagem: Inglês
10.1002/anie.200703161
ISSN1521-3773
AutoresTakato Mitsudome, Yusuke Mikami, Hisashi Funai, Tomoo Mizugaki, Koichiro Jitsukawa, Kiyotomi Kaneda,
Tópico(s)Layered Double Hydroxides Synthesis and Applications
ResumoAngewandte Chemie International EditionVolume 47, Issue 1 p. 138-141 Communication Oxidant-Free Alcohol Dehydrogenation Using a Reusable Hydrotalcite-Supported Silver Nanoparticle Catalyst† Takato Mitsudome Dr., Takato Mitsudome Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorYusuke Mikami, Yusuke Mikami Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorHisashi Funai, Hisashi Funai Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorTomoo Mizugaki Dr., Tomoo Mizugaki Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorKoichiro Jitsukawa Prof. Dr., Koichiro Jitsukawa Prof. Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorKiyotomi Kaneda Prof. Dr., Kiyotomi Kaneda Prof. Dr. [email protected] Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.html Research Center for Solar Energy Chemistry, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, JapanSearch for more papers by this author Takato Mitsudome Dr., Takato Mitsudome Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorYusuke Mikami, Yusuke Mikami Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorHisashi Funai, Hisashi Funai Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorTomoo Mizugaki Dr., Tomoo Mizugaki Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorKoichiro Jitsukawa Prof. Dr., Koichiro Jitsukawa Prof. Dr. Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.htmlSearch for more papers by this authorKiyotomi Kaneda Prof. Dr., Kiyotomi Kaneda Prof. Dr. [email protected] Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan, Fax: (+81) 6-6850-6260 http://www.cheng.es.osaka-u.ac.jp/kanedalabo/index_eng.html Research Center for Solar Energy Chemistry, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, JapanSearch for more papers by this author First published: 13 December 2007 https://doi.org/10.1002/anie.200703161Citations: 240 † This study was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology of Japan (18360389). This work was also supported by a Grant-in-Aid for Scientific Research on Priority Areas (no. 18065016, “Chemistry of Concerto Catalysis”) from the Ministry of Education, Culture, Sports, Science, and Technology (Japan). Some of the experiments were carried out at a facility in the Research Center for Ultrahigh Voltage Electron Microscopy, Osaka University. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract Additive free: Hydrotalcite-supported silver nanoparticles act as a highly efficient heterogeneous catalyst for the dehydrogenation of diverse alcohols (see picture) in the absence of any acceptors such as molecular oxygen, hydrogen peroxide, or unsaturated organic compounds. The solid Ag catalyst was readily reusable without any loss of activity and selectivity. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z703161_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume47, Issue1December 17, 2007Pages 138-141 RelatedInformation
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