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Artigo Revisado por pares
BIBTEX RIS

Copper(ii)-catalysed aerobic oxidation of primary alcohols to aldehydes

2003; Royal Society of Chemistry; Issue: 19 Linguagem: Inglês

10.1039/b308668b

ISSN

1364-548X

Autores

Patrick Gámez, Isabel W. C. E. Arends, J. Reedijk, Roger A. Sheldon,

Tópico(s)

Alkaloids: synthesis and pharmacology

Resumo

[CuBr2(2,2'-bipyridine)] catalyses the selective and very mild aerobic oxidation of primary alcohols to aldehydes in acetonitrile:water (2:1) in the presence of 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and a base as cocatalysts.

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