Artigo Acesso aberto Revisado por pares

On the growth of ammonium nitrate(III) crystals

1990; Elsevier BV; Volume: 100; Issue: 3 Linguagem: Inglês

10.1016/0022-0248(90)90242-d

ISSN

1873-5002

Autores

L.J.P. Vogels, H.A.M. Marsman, Marcel A. Verheijen, P. Bennema, M. Elwenspoek,

Tópico(s)

nanoparticles nucleation surface interactions

Resumo

The growth rate of NH4NO3 phase III crystals is measured and interpreted using two models. The first is a standard crystal growth model based on a spiral growth mechanism, the second outlines the concept of kinetical roughening. As the crystal becomes rough a critical supersaturation can be determined and from this the step free energy. The step free energy versus temperature turns out to be well represented by a Kosterlitz—Thouless type model. Further a phenomenological treatment of some peculiar growth observations is given.

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