Nitro alkanes in organic synthesis: An efficient stereoselective synthesis of (+)-trans whisky lactone and (+)-eldanolide from nitro alkane synthons and using bakers' yeast reduction as the key step

Artigo Revisado por pares

Nitro alkanes in organic synthesis: An efficient stereoselective synthesis of (+)-trans whisky lactone and (+)-eldanolide from nitro alkane synthons and using bakers' yeast reduction as the key step

1993; Elsevier BV; Volume: 49; Issue: 11 Linguagem: Inglês

10.1016/s0040-4020(01)80369-0

ISSN

1464-5416

Autores

B. K. SARMAH, Nabin C. Barua,

Tópico(s)

Chemical Synthesis and Analysis

Resumo

An efficient route using nitroalkane synthon 3a and 3b for the synthesis of optically pure R-(+)-trans whisky lactone, (+)-9 and R-(+)-eldanolide, (+)-10 is described. In a key step, bakers' yeast reduction is employed to get the required chirality.

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Nitro alkanes in organic synthesis: An efficient stereoselective synthesis of (+)-trans whisky lactone and (+)-eldanolide from nitro alkane synthons and using bakers' yeast reduction as the key step