Representation of one-dimensional motion in a morse potential by a quadratic hamiltonian
1983; Elsevier BV; Volume: 95; Issue: 2 Linguagem: Inglês
10.1016/0009-2614(83)85071-4
ISSN1873-4448
Autores Tópico(s)Molecular spectroscopy and chirality
ResumoA representation of the algebraic hamiltonian for the anharmonic Morse oscillator as a quadratic form, H = T1ω(12P2 + 12Q2), where P and Q are operators is derived. The commutator of P and Q is an operator that tends to i (times the identity operator) in the harmonic limit. Coherent states and anharmonic normal modes for a linear triatomic molecule are discussed as potential applications.
Referência(s)