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Catalytic Amide‐Mediated Methyl Transfer from Silanes to Alkenes in Fujiwara–Moritani Oxidative Coupling

2008; Wiley; Volume: 47; Issue: 22 Linguagem: Inglês

10.1002/anie.200800815

1521-3773

Waqar Rauf, John M. Brown,

Synthetic Organic Chemistry Methods

Intramolecular assistance: Carbon-bound trimethylsilyl groups are activated intramolecularly by a carbonyl group and can participate in Heck reactions under oxidative conditions. Good stereoselectivities are obtained for a range of di- and trisubstituted alkenes (see example). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z800815_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.