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Synthesis of Multielectron Ligands for Transition Metalsvia Spiro[cyclopropane-1,1?-indene]

1981; Wiley; Volume: 20; Issue: 1 Linguagem: Inglês

10.1002/anie.198101171

1521-3773

Karlheinz Berghus, Angelika Hamsen, Alfons Rensing, Annegret Woltermann, Thomas Kauffmann,

Surface Chemistry and Catalysis

The multielectron ligand contained in the stable Iron complex (1), was synthesized, as were many other ligands of this type, from the title compound. Ligands with indenyl groups form chiral complexes; these would be useful for the development of catalysts for asymmetrical homocatalysis.