Artigo Acesso aberto Revisado por pares

Rapid occurrence of sugar tricyclic orthoesters by acid catalyzed intramolecular orthotransesterification

2005; ARKAT USA, Inc.; Volume: 2005; Issue: 12 Linguagem: Inglês

10.3998/ark.5550190.0006.c13

ISSN

1551-7012

Autores

Oscar Moradei, Cecile du Mortier, Alicia Fernández Cirelli,

Tópico(s)

Biofuel production and bioconversion

Resumo

The preparation of 6-O-(tert-butyldiphenylsilyl)-α-D-glucopyranose 1,2,4-orthoacetate from 1,2-O-(1-exo-methoxyethylidene)-α-D-glucopyranose by acid catalyzed intramolecular orthotransesterification is described.A mechanism for the reaction is proposed.

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