Rapid occurrence of sugar tricyclic orthoesters by acid catalyzed intramolecular orthotransesterification
2005; ARKAT USA, Inc.; Volume: 2005; Issue: 12 Linguagem: Inglês
10.3998/ark.5550190.0006.c13
ISSN1551-7012
AutoresOscar Moradei, Cecile du Mortier, Alicia Fernández Cirelli,
Tópico(s)Biofuel production and bioconversion
ResumoThe preparation of 6-O-(tert-butyldiphenylsilyl)-α-D-glucopyranose 1,2,4-orthoacetate from 1,2-O-(1-exo-methoxyethylidene)-α-D-glucopyranose by acid catalyzed intramolecular orthotransesterification is described.A mechanism for the reaction is proposed.
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