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Single Pyramid Magnets: Dy 5 Pyramids with Slow Magnetic Relaxation to 40 K

2011; Wiley; Volume: 50; Issue: 29 Linguagem: Inglês

10.1002/anie.201101932

1521-3773

Robin J. Blagg, C.A. Muryn, Eric J. L. McInnes, Floriana Tuna, Richard E. P. Winpenny,

Organic and Molecular Conductors Research

Angewandte Chemie International EditionVolume 50, Issue 29 p. 6530-6533 Communication Single Pyramid Magnets: Dy5 Pyramids with Slow Magnetic Relaxation to 40 K† Dr. Robin J. Blagg, Dr. Robin J. Blagg School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorDr. Christopher A. Muryn, Dr. Christopher A. Muryn School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorProf. Eric J. L. McInnes, Corresponding Author Prof. Eric J. L. McInnes [email protected] School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorDr. Floriana Tuna, Dr. Floriana Tuna School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorProf. Richard E. P. Winpenny, Corresponding Author Prof. Richard E. P. Winpenny School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this author Dr. Robin J. Blagg, Dr. Robin J. Blagg School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorDr. Christopher A. Muryn, Dr. Christopher A. Muryn School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorProf. Eric J. L. McInnes, Corresponding Author Prof. Eric J. L. McInnes [email protected] School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorDr. Floriana Tuna, Dr. Floriana Tuna School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this authorProf. Richard E. P. Winpenny, Corresponding Author Prof. Richard E. P. Winpenny School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester, M13 9PL (U.K.), Fax: (+44) 161-275-4598Search for more papers by this author First published: 07 June 2011 https://doi.org/10.1002/anie.201101932Citations: 450 † We thank the EPSRC for funding and access to the Chemical Database Service at Daresbury. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Single-molecule magnets: A square-pyramidal pentametallic dysprosium cluster (see picture) was synthesized and showed slow magnetic relaxation at temperatures as high as 40 K. The thermal energy barrier to relaxation of magnetization of this single-molecule magnet is 530 K and is the largest yet observed for any d- or f-block cluster compound. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201101932_sm_miscellaneous_information.pdf201.1 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume50, Issue29July 11, 2011Pages 6530-6533 RelatedInformation