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Synthesis and catalytic properties of MIL-100(Fe), an iron( iii ) carboxylate with large pores

2007; Royal Society of Chemistry; Issue: 27 Linguagem: Inglês

10.1039/b704325b

1364-548X

Patricia Horcajada, Suzy Surblé, Christian Serre, Do‐Young Hong, You‐Kyong Seo, Jong‐San Chang, Jean‐Marc Grenèche, I. Margiolaki, Gérard Férey,

Covalent Organic Framework Applications

The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel–Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe).