Highly Efficient Gold Nanoparticle Catalyzed Deoxygenation of Amides, Sulfoxides, and Pyridine N ‐Oxides
2011; Wiley; Volume: 17; Issue: 6 Linguagem: Inglês
10.1002/chem.201003109
ISSN1521-3765
AutoresYusuke Mikami, Akifumi Noujima, Takato Mitsudome, Tomoo Mizugaki, Koichiro Jitsukawa, Kiyotomi Kaneda,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoChemistry – A European JournalVolume 17, Issue 6 p. 1768-1772 Communication Highly Efficient Gold Nanoparticle Catalyzed Deoxygenation of Amides, Sulfoxides, and Pyridine N-Oxides Yusuke Mikami, Yusuke Mikami Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorAkifumi Noujima, Akifumi Noujima Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorDr. Takato Mitsudome, Dr. Takato Mitsudome Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorDr. Tomoo Mizugaki, Dr. Tomoo Mizugaki Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorProf. Dr. Koichiro Jitsukawa, Prof. Dr. Koichiro Jitsukawa Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorProf. Dr. Kiyotomi Kaneda, Corresponding Author Prof. Dr. Kiyotomi Kaneda kaneda@cheng.es.osaka-u.ac.jp Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan) Research Center for Solar Energy Chemistry Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this author Yusuke Mikami, Yusuke Mikami Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorAkifumi Noujima, Akifumi Noujima Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorDr. Takato Mitsudome, Dr. Takato Mitsudome Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorDr. Tomoo Mizugaki, Dr. Tomoo Mizugaki Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorProf. Dr. Koichiro Jitsukawa, Prof. Dr. Koichiro Jitsukawa Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this authorProf. Dr. Kiyotomi Kaneda, Corresponding Author Prof. Dr. Kiyotomi Kaneda kaneda@cheng.es.osaka-u.ac.jp Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan) Research Center for Solar Energy Chemistry Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan), Fax: (+81) 6-6850-6260Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)Search for more papers by this author First published: 12 January 2011 https://doi.org/10.1002/chem.201003109Citations: 87Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract HAPpy catalysts: Hydroxyapatite-supported gold nanoparticles efficiently catalyze the deoxygenation of amides, sulfoxides, and pyridine N-oxides, with silanes as reductants, to give the corresponding products with excellent turnover numbers (see graphic). Furthermore, this catalyst is easily recovered and reused without any loss of efficiency. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description chem_201003109_sm_miscellaneous_information.pdf571.6 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume17, Issue6February 7, 2011Pages 1768-1772 RelatedInformation
Referência(s)