Portal de Periódicos da CAPES

High‐Performance Semiconductors based on Alkoxylnaphthyl End‐Capped Oligomers for Organic Thin‐Film Transistors

2008; Volume: 20; Issue: 24 Linguagem: Inglês

10.1002/adma.200800061

1521-4095

Qinghua Zhao, Tae Hoon Kim, Jong Won Park, Seul Ong Kim, Sung Ouk Jung, Jin Woo Kim, Taek Ahn, Yun‐Hi Kim, Mi Hye Yi, Soon‐Ki Kwon,

Advanced Memory and Neural Computing

Advanced MaterialsVolume 20, Issue 24 p. 4868-4872 Communication High-Performance Semiconductors based on Alkoxylnaphthyl End-Capped Oligomers for Organic Thin-Film Transistors† Qinghua Zhao, Qinghua Zhao School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorTae Hoon Kim, Tae Hoon Kim School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorJong Won Park, Jong Won Park School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorSeul Ong Kim, Seul Ong Kim School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorSung Ouk Jung, Sung Ouk Jung School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorJin Woo Kim, Jin Woo Kim Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea)Search for more papers by this authorTaek Ahn, Taek Ahn Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea)Search for more papers by this authorYun-Hi Kim, Corresponding Author Yun-Hi Kim [email protected] Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea) Yun-Hi Kim, Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea). Mi Hye Yi, Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea). Soon-Ki Kwon, School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea).Search for more papers by this authorMi Hye Yi, Corresponding Author Mi Hye Yi [email protected] Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea) Yun-Hi Kim, Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea). Mi Hye Yi, Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea). Soon-Ki Kwon, School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea).Search for more papers by this authorSoon-Ki Kwon, Corresponding Author Soon-Ki Kwon [email protected] School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea) Yun-Hi Kim, Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea). Mi Hye Yi, Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea). Soon-Ki Kwon, School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea).Search for more papers by this author Qinghua Zhao, Qinghua Zhao School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorTae Hoon Kim, Tae Hoon Kim School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorJong Won Park, Jong Won Park School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorSeul Ong Kim, Seul Ong Kim School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorSung Ouk Jung, Sung Ouk Jung School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea)Search for more papers by this authorJin Woo Kim, Jin Woo Kim Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea)Search for more papers by this authorTaek Ahn, Taek Ahn Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea)Search for more papers by this authorYun-Hi Kim, Corresponding Author Yun-Hi Kim [email protected] Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea) Yun-Hi Kim, Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea). Mi Hye Yi, Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea). Soon-Ki Kwon, School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea).Search for more papers by this authorMi Hye Yi, Corresponding Author Mi Hye Yi [email protected] Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea) Yun-Hi Kim, Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea). Mi Hye Yi, Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea). Soon-Ki Kwon, School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea).Search for more papers by this authorSoon-Ki Kwon, Corresponding Author Soon-Ki Kwon [email protected] School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea) Yun-Hi Kim, Department of Chemistry Gyeongsang National University and Research Institute of Nature Science (RINS) Jinju 660-701 (Korea). Mi Hye Yi, Information & Electronics Polymer Research Center (I & E PRC) Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea). Soon-Ki Kwon, School of Materials Science and Engineering Engineering Research Institute (ERI) Gyeongsang National University Jinju 660-701 (Korea).Search for more papers by this author First published: 16 December 2008 https://doi.org/10.1002/adma.200800061Citations: 37 † This work was supported by the 21st Century Frontier R&D Program funded by the Ministry of Knowledge Economy of the Korean government. Q. H. Zhao, T. H. Kim, J. W. Park, S. O. Kim, and Prof. S. O. Jung acknowledge the financial support of the Ministry of Education and Human Resources via the BK 21 Program and Human Resources Training Project for Stategic Technology. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Small-fused acenes with an electron-donating alkoxyl naphthyl end-capper, which can tune the electronic properties and increase stacking by self-assembly, are synthesized by a simple process and fabricated into organic thin film transistors. In particular, hexyloxynaphthalene-end-capped anthracene, AN-ANE (see figure), shows field effect mobility three times that of pentacene under optimized conditions. References 1a G. Horowitz, Adv. Mater. 1998, 10, 365. 1b C. D. Dimitrakopoulos, P. R. L. Malenfant, Adv. Mater. 2002, 14, 99. 1c G. Horowitz, J. Mater. Chem. 1999, 9, 2021. 1d G. H. Gelinck, T. C. T. Geuns, D. M. de Leeuw, Appl. Phys. Lett. 2000, 77, 1487. 1e C. J. Drury, C. M. J. Mutsaers, C. M. Hart, M. Matters, D. M. de Leeuw, Appl. Phys. Lett. 1998, 73, 108. 1f G. B. Blanchet, Y.-L. Loo, J. A. Rogers, F. Gao, C. R. Fincher, Appl. Phys. Lett. 2003, 82, 463. 1g D. Voss, Nature 2000, 407, 442. 1h S. J. Lee, M. H. Choi, S. H. Han, D. J. Choo, J. Jang, S. K. Kwon, Org. Electron. 2008, 9, 72. 1i D. S. Chung, D. H. Lee, C. W. Yang, K. P. Hong, C. E. Park, J. W. Park, S. K. Kwon, Appl. Phys. Lett. 2008, 93, 033303-1. 1j Y. N. Li, T. H. Kim, Q. H. Zhao, E. K. Kim, S. H. Han, T. H. Kim, J. Jang, S. K. Kwon, J. Polym. Sci, Part A: Polym. Chem. 2008, 46, 5115. 2a G. Horowitz, M. E. Hajlaoui, Adv. Mater. 2000, 12, 1046. 2b Y. S. Yang, T. Zyung, Macromol. Res. 2002, 10, 75. 2c F. C. Chen, C. W. Chu, J. He, Y. Yang, Appl. Phys. Lett. 2004, 85, 3295. 2d H. Moon, R. Zeis, E. J. Borkent, C. Besnard, A. J. Lovinger, T. Siegrist, C. Kloc, Z. N. Bao, J. Am. Chem. Soc. 2004, 126, 15322. 2e T. Graves-Abe, Z. N. Bao, J. C. Sturn, Nano Lett. 2004, 4, 2489. 2f H. E. Katz, Chem. Mater. 2004, 85, 5084. 2g N. Drolet, J. F. Morin, N. Leclerc, S. Wakim, Y. Tao, M. Leclerc, Adv. Funct. Mater. 2005, 15, 1671. 2h J. Locklin, M. M. Ling, A. Sung, M. E. Roberts, Z. N. Bao, Adv. Mater. 2006, 18, 2989. 2i V. A. L. Roy, Y. G. Zhi, Z. X. Xu, S. C. Yu, P. W. H. Chen, C. M. Che, Adv. Mater. 2005, 17, 1258. 2j J. H. Park, D. S. Chung, J. W. Park, T. Ahn, H. Kong, Y. K. Jung, J. H. Lee, M. H. Yi, C. E. Park, S. K. Kwon, H. K. Shin, Org. Lett. 2007, 9, 2573. 2k T. T. M. Dang, S. J. Park, J. W. Park, D. S. Chung, C. E. Park, Y. H. Kim, S. K. Kwon, J. Polym. Sci, Part A: Polym. Chem. 2007, 45, 5277. 2l K. Oikawa, H. Monobe, K. Nakayama, T. Kimoto, K. Tsuchiya, B. Heinrich, D. Guillon, Y. Shimizu, M. Yokoyama, Adv. Mater. 2007, 19, 1864. 2m D. S. Chung, S. J. Lee, J. W. Park, D. B. Choi, D. H. Lee, J. W. Park, S. C. Chin, Y. K. Kim, S. K. Kwon, C. E. Park, Chem. Mater. 2008, 20, 3450. 3a H. E. Katz, Z. Bao, S. L. Gilat, Acc. Chem. Res. 2001, 34, 359. 3b F. Yassar, R. Hajlaoui, G. Horowitz, F. Deloffre, B. Servet, S. Ries, P. Alnot, J. Am. Chem. Soc. 1993, 115, 8716. 3c D. J. Gundlach, Y. Y. Lin, T. N. Jackson, D. G. Schlom, Appl. Phys. Lett. 1997, 71, 3853. 4 J. G. Laquidanum, H. E. Katz, A. J. Lovinger, A. Dodabalapur, Adv. Mater. 1997, 9, 36. 5 K. Ito, T. Suzuki, Y. Sakamoto, D. Kubota, Y. Inoue, F. Sato, S. Tokito, Angew. Chem. Int. Ed. 2003, 42, 1159. 6 J. A. Merlo, C. R. Newman, C. P. Gerlach, T. W. Kelley, D. V. Muyers, S. E. Fritz, M. F. Toney, C. D. Frisbie, J. Am. Chem. Soc. 2005, 127, 3997. 7 H. K. Tian, J. W. Shi, D. H. Yan, L. X. Wang, Y. H. Geng, F. S. Wang, Adv. Mater. 2006, 18, 2149. 8 H. Klauk, U. Zschieschang, R. T. Weitz, H. Meng, F. P. Sun, G. Nunes, D. E. Keys, C. R. Fincher, Z. Xiang, Adv. Mater. 2007, 19, 3882. 9 H. S. Kim, Y. H. Kim, T. H. Kim, Y. Y. Noh, S. Pyo, M. H. Yi, D. Y. Kim, S. K. Kwon, Chem. Mater. 2007, 19, 3561. 10 H. Kalauk, M. Halik, U. Zschieschang, G. Schmid, W. Radlik, W. Weber, J. Appl. Phys. 2002, 92, 5259. 11 T. W. Kelley, D. V. Muyres, P. E. Baude, T. P. Smith, T. D. Jones, Mater. Res. Soc. Symp. Proc. 2003, 771, 169. 12 A. J. Bard, L. R. Faulkner, Electrochemical Methods—Fundamentals and Applications, Wiley, New York 1984. 13 E. Lim, B. Jung, H. K. Shim, Macromolecules 2003, 36, 4288. Citing Literature Volume20, Issue24December 17, 2008Pages 4868-4872 ReferencesRelatedInformation